I've never seen sunsets like those in Arizona, and the best by far was at Gates Pass. Easily accessed off of Kinney, just park and enjoy the overlook. There are trails both going up (can be a little trecherous) and down to the road below. While the gazebo off the parking lot offers a shaded view of the sunset, if, while facing west you follow the trail to the west a few hundred feet up a small hill, you will get a completely unobstructed view of the setting sun. Also, from the parking lot if you face east there is a nice view of the city through the other end of the pass.
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